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Cr4+:YAG for passive Q-Switching of solid-state lasers

 

Passive Q-Switching is preferred for simplicity of manufacturing and operation, low cost and reduced system size and weight. Cr4+:YAG (Y3Al5O12) is an excellent crystal for passively Q-switching diode pumped or lamp-pumped Nd:YAG, Nd:YLF, Yb:YAG or other Nd and Yb doped lasers at wavelength from 1.0 to 1.2 mm.

 

Because of its chemically stability, durability, UV resistance, good thermal conductivity, and high damage threshold (> 500 MW/cm2), it will replace traditional materials such as LiF, organic Dye and color centers.

 

Physical and Optical Properties:

Chemical FormulaCr 4+:Y3 A15 O12
Crystal StructureCubic garnet
Recovery time8.5 µs
Hardness Mohs8.5
Density4.56g/cm3
Orientation[100]+/-10°
Thermal conductivity12.13w/m/k
Refractive index1.82 @ 1064nm

Optical Properties:

Base state absorption cross sectionσ s 1 =4.3x10-18 cm2
Emission state absorption cross sectionσ s 2 =8.2x10-19 cm2
Fluorescence lifetime3.4us

Capabilities:

Cr4+ dopant concentration 0.5 mol% ~ 3 mol%
Aperture2x2 ~ 14x14mm
Initial transmission10% ~ 99%

Typical Specification and Tolerance:

Dimension tolerance (W ± 0.1mm) x (H ± 0.1mm) x (L + 0.2mm/-0.1mm)
Flatness< λ/8 @ 633nm
Scratch/Dig codebetter than 10/5 Scracth/dig per MIL-O-13830A
Parallelism< 20 arc seconds
Perpendicularity< 5 arc minutes
Wavefront distortionless than λ/8 @ 633nm
Clear aperture> 90% central area
CoatingAnti-reflective